Technoeconomics of thermochemical processing of biomass helps bridge the gap between small scale biomass-to-liquid (BTL) process systems and large scale BTL systems, i.e. to identify if the process systems are technically and economically viable for commercialization. The objective of our technoeconomic analysis is to determine the costs of producing advanced biorenewable fuels via thermochemical pathways and the costs of building the process plants. The technical aspects of the BTL technologies are simulated at large scale using computer modeling software and the results allow for the evaluation of economic aspects such as biorefinery plant costs and biofuel production costs. Biorenewable technologies being explored in the current project include biomass fast pyrolysis and gasification based processes to generate a suite of transportation fuels including Fischer Tropsch diesel (Green diesel), ethanol, methanol, dimethyl ether, and hydrogen among others.
Fast pyrolysis is a rapid (few seconds), mild temperature (about 500°C) process that converts biomass into gas, solid, and liquid products. Pyrolysis gas is a low heating value gas that can be employed to provide process heat. Bio-char, which can comprise up to 20 weight % of the product, has similar characteristics to charcoal; it can be employed as substitute for coal (as fuel), but more promising options involve farm land fertilization and carbon sequestration. Finally, bio-oil (more than 70% weight yield possible) is a highly viscous, dark liquid composed of numerous organic components. Bio-oil can be upgraded to transportation fuels through various processes and therefore holds great promise as a biomass densification agent. By densifying biomass into bio-oil, transportation costs, which could limit the size of biomass based refineries, would be drastically reduced. An economic analysis on distributed small fast pyrolysis plants vs. a large centralized fast pyrolysis plant has been conducted and reported.
Gasification is less rapid, higher temperature (800-900°C) process producing a synthesis gas and solid char. This part of the project is researching the feasibility of a 2000 dry ton per day biorefinery with biomass pretreatment setups including drying and grinding, gasifier setups including high and low temperature (slagging and non-slagging), synthesis gas cleaning setups including hot and cold gas cleaning, and fuel synthesis setups including Fischer-Tropsch and methanol-to-gasoline catalytic processes. ASPEN PLUS™ (Advanced System for Process Engineering) software is being used to simulate the system and generate a visual representation of the mass and energy balances whereby optimization can occur. From there sizing and costing of equipment can be completed. Sensitivity analysis whereby a process parameter (such as feedstock cost, feedstock moisture, level of recycle streams, or catalyst cost) is varied across a range resulting in a range of fuel production costs.
Technoeconomics of biorenewable technologies allows for better understanding of the cost associated with producing transportation fuels from biomass. Given the variety of potential approaches to producing biofuels, it is important to be able to compare all the technologies on an equal basis. Meaningful technical and cost comparisons will aide in deciding which processes hold the most promise moving forward.
Publications:
Wright M and Brown R. C., “Comparative economics of biorefineries based on the biochemical and thermochemical platforms” Biofuels Bioproducts and Biorefining 1:49–56 (2007).
Wright M. and Brown R. C., “Establishing the Optimal Sizes of Different Kinds of
Biorefineries” Biofuels, Bioproducts and Biorefining 1:191-207 (2007)
These publications available online at:
Biofuels, Bioproducts and Biorefining
Principal Investigators:
Dr. Robert Brown (rcbrown
iastate.edu)
Dr. Justinus Satrio (jasatrio
iastate.edu)
Mark Wright (markjet7
iastate.edu)
Ryan Swanson (rynswnsn
iastate.edu)
Research Supported by: Conoco Phillips and United States Department of Agriculture